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Research PaperResearchia:202609.07039

Diffusion under competing bulk and surface stopping mechanisms

Yilin Ye

Abstract

We investigate reflected diffusion in a bounded domain subject to two independent, competing stopping mechanisms: an exponentially distributed bulk lifetime of rate $p$ and a surface reaction triggered when the boundary local time exceeds an independent exponential threshold of rate $q$. Denoting by $T$ the stopping time and by $L$ the acquired boundary local time at stopping, we derive their marginal distributions, joint Laplace transform, and complete hierarchy of mixed moments. These statisti...

Submitted: September 7, 2026Subjects: Chemistry; Chemistry

Description / Details

We investigate reflected diffusion in a bounded domain subject to two independent, competing stopping mechanisms: an exponentially distributed bulk lifetime of rate pp and a surface reaction triggered when the boundary local time exceeds an independent exponential threshold of rate qq. Denoting by TT the stopping time and by LL the acquired boundary local time at stopping, we derive their marginal distributions, joint Laplace transform, and complete hierarchy of mixed moments. These statistics are determined by the splitting probability ฯ†ฯ† that surface reaction occurs before bulk decay. In particular, we establish the identity p\expectT+q\expectL=1p\expect{T}+q\expect{L}=1 and show that the cumulative risk pT+qLpT+qL is exponentially distributed with unit rate. We further obtain equivalent representations of ฯ†ฯ† in terms of the Robin-Laplacian and the generalized Steklov spectra. Explicit results for a three-dimensional ball reveal how competing rates p,qp,q control ฯ†ฯ† and the (T,L)(T,L) statistics. Monte Carlo simulations test the universal cumulative-risk law.


Source: arXiv:2609.05247v1 - http://arxiv.org/abs/2609.05247v1 PDF: https://arxiv.org/pdf/2609.05247v1 Original Link: http://arxiv.org/abs/2609.05247v1

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Date:
Sep 7, 2026
Topic:
Chemistry
Area:
Chemistry
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