Gas-phase chemistry of $\mathrm{C}_3\mathrm{H}_3^+$: a key building block for carbon mass growth in space

The gas-phase chemistry of $\mathrm{C}_3\mathrm{H}_3^+$ plays a central role in the growth of carbonaceous species across a wide range of environments, from combustion systems to interstellar media. However, the presence of multiple isomers, primarily the linear propargyl cation and the cyclic cyclopropenyl cation, has so far prevented the determination of reliable isomer-specific reaction kinetics. In this work, we combine tunable vacuum-ultraviolet (VUV) photoionization with controlled ion--molecule reaction measurements to selectively produce and probe the reactivity of $\mathrm{C}_3\mathrm{H}_3^+$ isomers. By employing a titration approach, we extract isomer-specific reaction rate coefficients and branching ratios for reactions of $\mathrm{C}_3\mathrm{H}_3^+$ with $\mathrm{C}_2\mathrm{H}_4$, $\mathrm{C}_3\mathrm{H}_4$, and $\mathrm{C}_3\mathrm{H}_6$. Our results demonstrate a strong contrast in reactivity: the most stable cyclic isomer is found to be essentially unreactive under the investigated conditions, whereas the linear isomer exhibits efficient and diverse chemistry leading to the formation of larger hydrocarbon ions. In particular, the formation of $\mathrm{C}_6\mathrm{H}_5^+$ is observed, providing an important intermediate in pathways toward aromatic species. These findings help resolve long-standing ambiguities in previously reported rate coefficients and provide new quantitative constraints for kinetic and astrochemical models. More broadly, this work highlights the importance of isomer-specific chemistry in carbon growth processes and demonstrates the effectiveness of VUV-based photoionization methods for disentangling complex reaction networks in the gas phase.

Source: arXiv:2610.11985v1 - http://arxiv.org/abs/2610.11985v1 PDF: https://arxiv.org/pdf/2610.11985v1 Original Link: http://arxiv.org/abs/2610.11985v1