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Research PaperResearchia:202602.03142[Chemistry > Chemistry]

A third law of thermodynamics is an unnecessary complexity

José-María Martín-Olalla

Abstract

This paper elaborates on the implications of the relationship between the Second and Third Laws and provides a comprehensive formal and historical justification for the logical redundancy of the Nernst heat theorem. By revisiting the Nernst-Einstein debate, the underlying hypotheses that lead to the traditional view of the Third Law as an independent postulate are examined. It is argued that the historical rejection of Nernst's proof -- motivated by Einstein's insistence on the practical non-performability of cycles at absolute zero -- overlooks the fact that a universal Second Law already precludes such cycles, rendering an independent Third Law an unnecessary complexity. Ultimately, the Nernst theorem is shown to be an essential consistency regulator rather than an independent physical discovery.


Source: arXiv:2602.03244v1 - http://arxiv.org/abs/2602.03244v1 PDF: https://arxiv.org/pdf/2602.03244v1 Original Article: View on arXiv

Submission:2/3/2026
Comments:0 comments
Subjects:Chemistry; Chemistry
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arXiv: This paper is hosted on arXiv, an open-access repository
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